The first example of direct oxidation of sulfides to sulfones by an osmate molecular oxygen system.
نویسندگان
چکیده
Osmate-exchanged Mg-Al layered double hydroxides catalysed the delivery of two oxygen atoms simultaneously via a 3 + 1 cycloaddition to sulfide to form sulfone directly for the first time, reminiscent of 3 + 2 cycloaddition in asymmetric dihydroxylation reactions.
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ورودعنوان ژورنال:
- Chemical communications
دوره 6 شماره
صفحات -
تاریخ انتشار 2003